John Gill Commentary Luke 9:33

"And it came to pass, as they were parting from him, Peter said unto Jesus, Master, it is good for us to be here: and let us make three tabernacles; one for thee, and one for Moses, and one for Elijah: not knowing what he said." — Luke 9:33 (ASV)

And it came to pass, as they departed from him
That is, as Moses and Elias departed from Christ; or "when they began to depart", as the Syriac version renders it; or "would depart", as the Arabic and Persic versions; seemed desirous of going, or made some signal or other by which the disciples perceived they were about to go; for, as yet, they were not gone;

Peter said unto Jesus, master, it is good for us to be here, let us
make three tabernacles, one for thee, and one for Moses, and one for
Elias; (See Gill on Matthew 17:4)

not knowing what he said ,
nor "what to say", as Mark observes, being in a surprise, and not in a situation to consider and weigh things well, whether what he said was right and proper, or not; (See Gill on Matthew 17:4)